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書本:ORGANIC CHEMISTRY 作者:Janice Gorzynski Smith 頁數:P.134 Steric strain is an increase in energy resulting when atoms are forced too close to one another. 想請問這句話是什麼意思.感謝解答 Torsional strain is an increase in energy caused by eclipsing interactions. 想請問Steric strain跟Torsional strain的差異與涵義.感謝 -- ※ 發信站: 批踢踢實業坊(ptt.cc) ◆ From: 220.131.141.1
chiehly:第一個應該是指在環烷時扭曲所造成的能量增加 10/17 23:55
chiehly:像環丁烷是sp3角度為109.5但卻要扭為90度 10/17 23:57
chiehly:對不起,我剛剛說的應該是第二個 10/18 00:02
chiehly:第一個是指在newman構型時兩團原子呈eclipsed時 10/18 00:03
hohohahahuhu:感謝 10/18 00:12