推 radiohead627:我同學說因為carbonyl的關係所以不會形成epoxide 02/13 22:55
推 shok:會啦 應該是epoxide 02/14 00:30
※ 引述《radiohead627 ( 香蕉勇士)》之銘言：
: 2-cyclohexenone 跟 H2O2 ,NaOH 反應
: 產物是啥?
: 應該不會是epoxide吧 有點懷疑
: thx
you got it!
the C=C of the alpha, beta-unsaturated carbonyl system showed
the polarized electronic nature.
the peroxide, generated from H2O2 and NaOH, is a good nucleophile
for 1,4-addition reaction.
as OOH- attacted on beta-carbon, the enloate back-attacked onto the
peroxide to release a hydroxide and to form the alpha-carbonyl oxirane.
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