[問題]有機化學問題

[tm005002 (小高)]

請教各位大大，小弟做題目卡住了> <




Propose structure for hydrocarbon that give the product of CO2，

CH3COCH2COOH and CH3COCH3 on oxidative cleavage by KMnO4 ?


(A) 3,5-dimethyl-hexa-1,5-diene


(B) 2,5-dimethyl-hexa-1,4-diene


(C) 2,5-dimethyl-hexa-2,5-diene


(D) 1,5-dimethyl-hexa-1,4-diene



跪求大大指點 Q____Q

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推 lancer1668:hint: oxidative cleavage會把C=C雙鍵切成兩個C=O
推 lancer1668:如果是接=CH2的話就會變成CO2，-C(H)=的話就會變成COOH
→ lancer1668:B/C都可以?
→ tm005002:噢XDD  感謝~我畫畫看 因為我沒念到KMnO4也可以這樣切
→ lancer1668:想成是C=C → HO-C-C-OH →後續氧化
推 Rentch:c不對 名字不對