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※ 引述《sugarlesss (girl)》之銘言: : 考完剛到家! 來問幾題一直耿耿於懷的問題>< : 1. Three flasks, 1.0L , STP, A裝:He B: O2 C: H2 : How many of the flasks at STP are less dense than air at STP ? : 2. The majority of shell electron transition in molecules occur in the _____ : region of the electromagnetic spectrum : A) IR B) X rays C) UV D) microwave : 3. 電池 Cu^2+ + 2Ag → 2Ag^+ + Cu : 請問分別加 Ag^+ 或 Cu^2+ 會影響 cell potential 嗎? : 4. An ideal gas expands to the vacuum isothermally and irreveribly : W is A) <0 B) >0 C) =0 D) more imformation is needed : △U is A) <0 B) >0 C) =0 D) more imformation is needed : △G is A) <0 B) >0 C) =0 D) more imformation is needed : △Ssys is A) <0 B) >0 C) =0 D) more imformation is needed 恆溫不可逆膨脹 恆溫內能=0 而不可逆 G大於0(這裡沒註明是不是系統的自由能,有爭議) Ssys>0 膨脹做負功 所以W<0 以上 : 以上,請求板大解惑! -- ※ 發信站: 批踢踢實業坊(ptt.cc) ◆ From: 118.168.236.79
JL12:凡自發過程必不可逆,故G<0 07/16 23:50