課程名稱︰高分子化學
課程性質︰選修
課程教師︰謝國煌
開課學院：工學院
開課系所︰化工系
考試日期（年月日）︰2012.1.12
考試時限（分鐘）：120分鐘
是否需發放獎勵金：是
（如未明確表示，則不予發放）
試題 :
1.Describe the reaction mechanism of the ring-opening polymerization without
ring cleavage. (10%)
2.Describe the synthesis the Poly(ethylene oxide) by anionic catalyst(X+Y-
or M+OR-). (10%)
3.How to synthesis the Poly(tetramethylene oxide) from tetrahydrofuran in
the presence of Lewis acid (PF5) with the traces of water. (10%)
4.How to synthesis the Poly(vinyl alcohol) by side-group modification process.
(5%)
5.Describe four advantages for polymer-supported organic reactions. (10%)
6.If you have a photoresist reaction as
—(CH2-CH)n— —(CH2-CH)n—
丨 丨
／＼ hν ／＼
∣Ｏ∣ －－－→ ∣Ｏ∣
＼／ –CO ＼／
丨 丨
O OH
丨
C==0
丨
H
How do you use this resist as a positive and as a a negative resist,
respectively. (15%)
7.Why can we use the following simple equation to represent the condensation
polymerization (5%)
O O
╱╲╱╲ + ╱╲╱╲ → ╱╲╱╲∥ ╱ ╲╱╲╱ + H20↗
COOH OH C
8.Describe the rate equation of polyesterification and express its conversion
＿
(P) and degree of polymerization (DP). (10%)
9.Describe the propagation reactions of monomer M1 and M2 and derive the
equation for the relationship between the molar fraction ratio in the
polymer (f1/f2) and that in reaction mixture (F1/F2). (10%)
10.(a) Describe the reaction mechanism of anionic polymerization and its
characteristic during the reaction and final product. (5%)
(b) Derive the rate of polymerization to give the [M] as the function of
time t. (5%)
(c) Derive the average kinetic chain length (ν) and average degree of
＿
polymerization (DP). (5%)
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