課程名稱︰有機化學乙上 1st期中
課程性質︰必修
課程教師︰陳平
開課學院：生農學院
開課系所︰農化系
考試日期（年月日）︰102/10/17
考試時限（分鐘）：100分鐘
是否需發放獎勵金：是
（如未明確表示，則不予發放）
試題 :
Ⅰ.Full in the blanks. (7pts)
1.There are ____electrons in the outermost electron shell for Selenium.
2.There are ____sp3 hybridized carbons and ____ sp2 hybridized
carbons in the compound below.
"2-(diethylamino)ethyl 4-aminobenzoate"的圖
3.There are ____primary hydrogens.
____secondary hydrogens.
____teriary hydrogens.
____quaternary carbons in the compound below.
"2,2,4-Trimethylpentane"的圖
Ⅱ.Selections(17pts)
1.Please circle the more electroneative elememt in each row.(3pts)
Li C
Cl C
Na H
2.Please circle the molecule with the higher boiling point each row.(2pts)
Propane n-Hexane
2,2-Dimethylbutane n-Hexane
3.Please circle the more stable compound (1pts)
Cyclopentane Ethylcyclopropane
4.Please circle the compound with the higher dipole moment in each row.(2pts)
Hydroquinone Resorcin
Carbonyl chloride Methanal
5.Please circle the more stable species.(5pts)
CH3(CO)CH2- CH3C(O-)=CH2
CH2=CHCH(+)CH3 CH2(+)CH=CHCH3
O(-)N(+)(=CH2)O(-) O=N(+)(CH2(-))O(-) (N為中心原子 sp3外接O,O,C)
CH3CH2O(-) 苯酚陰離子
CH2=CHCH=CHCH(+)CH3 CH2=CHCH(+)CH=CHCH3
6.Please circle the group with higher priority
苯基 乙炔基
三級丁基 乙烯基
氰基 胺基
羧基 醛基
III.Stereoisomer identification.Please indicate the the relationship between
the following pairs of compounds.("i"dentical,"c"onstitutional,
"d"iastereomer,"e"nantiomer.)(5pts)
http://ppt.cc/Uotv
IV.Prochirality.Please assign the prochiral hydrogens and the prochiral
faces for the two following compounds, respectively.(4pts)
http://ppt.cc/Jk4r
V. Structure Drawing. Draw the skeletal structure including stereochemistry
with lone pairs for the following compounds.(38pts)
1.C6H5-N3
2.H3C-NC
3.(S)-3,3-diethyl-2,5-dimethylnonane
4.(S)-4-isopropyl-2-methylheptane
5.(R)-3,3,5-trimethyloctane
6.(1S,3R)-1-ethyl-3-methylcycloheptane
7.(1S,3S)-1-bromo-3-methylcyclohexane
8.(1S,3R)-1-ethyl-3-methylcyclopentane
9.(S)-3-chloro-1-pentane
10.Meso form of 3,5-heptanediol
VI.Newman projection.Please answer the following questions regarding the
following compounds.(13pts)
http://ppt.cc/uH1o
1.Please draw the Newman projection of lowest energy conformer.(4)
2.In general, the _____conformation is lower in energy.(1)
3.Please provide estimates for the following interrations.(8)
Please include units.
A: B: C: D:
http://ppt.cc/5vno
VII.Chair Coformation.Please draw the more stable chair coformation for
following compounds.(14pts)
http://ppt.cc/o-IV
VIII.Reaction Products.Please draw the skeletal strcture with lone pairs for
the products of following reactions.(12pts)
http://ppt.cc/TmBY
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※ 編輯: Ketsu24 來自: 118.166.251.186 (11/25 00:53)