課程名稱︰普通化學甲
課程性質︰系上必修
課程教師︰林萬寅
開課學院:理學院
開課系所︰物理系
考試日期(年月日)︰09.03.25
考試時限(分鐘):15min
是否需發放獎勵金:是
(如未明確表示,則不予發放)
試題 :
1. Butadiene (C4H6) reacts to form its dimer (C8H12) at 500 K according to the
equation: 2 C4H6(g) → C8H12(g). The plot of 1/[C4H6] vs. time is linear as
shown below. Answer the following equestions. (R = 8.31J.K^-1.mol^-1) 20%
圖:[C4H6]的倒數與時間成正比 斜率:0.05
(a) Give the rate law for the reaction. What is the order of the reaction?
(b) Give the integrated rate law of the reaction.
(c) Find the rate constant of the reaction.
(d) Calculate the initial rate law for the disappearance of C4H6
(e) What is the half-life of the reaction if [C4H6]0 = 0.020 M?
(f) If the rate constant of the reaction is 0.04 M^-1.s^-1 at 110K. Find the
activation energy of the reaction.
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