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課程名稱︰有機金屬化學
課程性質︰選修
課程教師︰劉緒宗
開課學院：理學院
開課系所︰化學系
考試日期（年月日）︰98/06/17
考試時限（分鐘）：120
是否需發放獎勵金：yes
（如未明確表示，則不予發放）
試題 :
命題者︰客座副教授 西原康師
Answer the following questions.(註)
Chapter 1
Describe each advantages and disadvantages points in the homogeneousand the
heterogeneous catalysts. (You may draw the table, or write sentences.)
Chapter 2
Explain with the figures in detail by selecting two from the following
fundamental five reactions in organometallic chistry. (oxidative addition,
reductive elimination, migratory insertion, β-hydrogen abstraction, and
transmetallation.)
Chapter 3
There exist four types of hydroformylation reactions (oxo process) with the
homogeneous catalysts. Explain one of them in detail.
Chapter 4
Show three equations and the net equation in the Monsanto processes.
Chapter 5
Describe reaction schemes and their catalytic cycle in the Ni-catalyzed addtion
reaction of HCN to buta-1,3-diene as much as you can. (You may draw the scheme,
or write sentences.)
Chapter 6
Explain the Ziegler-Natta catalyst by using all of the following vocabularies.
(co-catalyst, polypropylene, and active site.)
Chapter 7
Select one of the following three persons, and explain in detail the contents
of his chemistry related to the Noble Prize in Chemistry in 2001. (Knowles,
Noyori, Sharpless)
Chapter 8
Write the impression to the class in English by Japanese professor.
註︰試題中的章節是Robin Whyman, Applied Organometallic Chemistry and Catalysis,
Oxford University Press書中的內容 (不過考試是close book)
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