課程名稱︰普通化學甲
課程性質︰系定必修
課程教師︰陳藹然
開課學院：工學院
開課系所︰化工系
考試日期（年月日）︰96/10/30
考試時限（分鐘）：110分鐘
是否需發放獎勵金：是
（如未明確表示，則不予發放）
試題 :
1st Examination of General Chemistry A total score:120
1.Derive the energy levels of a particle of mass m in an one-dimensional box
of side L are E=(nh)^2/(8mL^2) n=1,2,....(10%)
Hints:standing wave and de Broglie relation.
2.Write five methods of producing H2.(10%)
3.Predict the products of each chemical reaction, and then balance the
equations.(15%)
(a)Na2O2+CO2→
(b)electrolysis of molten lithium hydride
(c)RbHCO3+H2SO4→
(d)CaC2+H2O→
(e)D2O+CsH→
(f)Sr+O2→
(g)thermal decomposition of CaCO3
4.Describe the evolution and histroy of atomic theory.(10%)
Hints:Bohr,Thomson.Dalton,current model,Rutherford.
5.Explain what is meant by each term:(a)absorbance and emission spectrum
(b)blackbody radiation (c)Zeff (d)radial probability (e)laser (20%)
6.Draw the orbital energy level diagrams for the hydrogen atom and for a
typical multi-electron atom, and discuss their differences.
7.(a)Arrange the following gaseous species in order of increasing radius, and
justify your decisions:Mg2+,P3-,S2-,F-,N3-. (5%)
(b)Arrange each set of elements in order of increasing magnitude of electron
affinity and justify your decisions:Na,Rb,P,C,K,Ge. (5%)
(c)Arrange the following gaseous species in order of increasing radius, and
justify your decisions:Ca2+,Cr2+,K+,Cr3+,Cs+. (5%)
8.(a)Classify these elements as either electrical insulations, electrical
conductors, or substances with intermediate conductivity:S,Ba,Fe,Al,B,O,C,P.
(b)what conclusions can you draw with regard to the relationship between
valence electron configurations, electronegativity and electrical properties?
(10%)
9.(a)Using arguments based on ionic size, charge, and chemical reactivity;
explain why beryllium oxide is amphoteric. (b)What element do you expect to
be most similar to beryllium in its reactivity? Explain your answer. (10%)
10.(a)What are quantum numbers? (b)what imformation they provide about the
spatial distribution of the eletron. (10%)
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