課程名稱︰分析化學丁
課程性質︰
課程教師︰何國榮
開課學院：
開課系所︰
考試日期（年月日）︰08/1/17
考試時限（分鐘）：140
是否需發放獎勵金：是
（如未明確表示，則不予發放）
試題 :
1.Explain that junction potential is a major factor to the error of pH
measurement.5%
2. 3+ - 2+ 0
Fe + e <=> Fe E = 0.68V in 1M H2SO4
- + - 2+ 0
MnO4 + 8H +5e <=> Mn + 4H2O E =1.507V
2+
Theoretical titration of 0.400L of 3.75mM Fe with 0.0200M KMnO4.
(a)Please draw the titration curve.
(b)Propose a method for the detection of end point.6%
3.For a chemical reaction A + B <=> C + D
0
please show the relationship between E and equilibrium constant.4%
4.Explain that stripping technique provides better sensitivity than
other voltammetry techniques.4%
5.Explain the concentration polarization and its effect to a galvanic
cell.6%
6.Explain that the 入 of excitation spectrum has slightly higher energy
than the 入 of emission spectrum.5%
7.Explain that intensity of light source is more critical to the sensitivity
of fluorescence than absorbance.4%
8.Explain that photodiode detector is often used in liquid chromatography.
4%
9.Explain that most commerical IR spectrometer is Fourier Transform IR.4%
10.Explain that furnace AA has better sensitivity than flame AA.4%
11.(a)Explain the operational principal of ICP.
(b)Describe the advantage of ICP/AES in comparsion with furnace AA.6%
12.Please show the temperature profile for a furnace atomic absorption
experiment and explain the purpose of each different part of the
heating profile.6%
13.Explain the technique of ion mobility spectrometer.4%
14.(a)Explain the difference between selected ion monitoring and selected
reaction monitoring.(b)Explain that SRM is more sensitive than SIM.6%
15Describe the two major factors affecting the resolution of chromatography
.4%
16.Based on van Deemter equation: H = A + B/u + C u
Explain the reason of using smaller particle in HPLC.4%
17.Based on van Deemter equation, explain the effect of open tubular
column inner diameter on resolution.4%
18.Describe the sample injection technique in HPLC.4%
19.Explain the utility of isotope peak in MS analysis.4%
20.In staircase voltammetry, explain that the current was msasured at
the end of each increase of voltage.4%
21.Explain that three electrode was used in controlled potential
electrolysis.4%
22.Explain that in potentiometry measurement, the current is very close
to zero.4%
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