[化學] 台大普化B&C(91-98)

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=普化B=
98
CEDCA DCACE BDDAA BACDA CDBAE


97
 1.E     BCE E   C   BCDF
 6.AB    C   ACE ACE C
11.D     BE  AF  D   F
16.ABCDE D   ACF CDE E
21.A     CD  C   B   C
26.(a)Ka=2.97
   (b)-2700J/mol
   (c)-79.1kJ/mol
   (d)0.00126 mol
27. 2.88
    4.39
    8.73
    10.00
28.(a)2.179x10^-18J
   (b)-1.216x10^6 J


96
I.
 1.b d   ab  bcd bcd
 6.d c   b   a   ab
11.c a   b   c   b
16.c abd abc b   d
21.b c   c

II.
1.(b)2
  (c)paramagnetic
2.(b)high-spin
3.(a)-46.19 ; -99.12 ; -16.65
  (b)exothermic
  (c)decrease
  (d)spontaneous


95
CAABB BAABB BBDCC BCCCC
1.(a)Al氧化,Cl2還原,6e
  (b)MnO4-還原, Fe2+氧化,5e
2.(c)1.13V


94
  I.cbdcb bbbdb baccb adbad cdcdc dbdbc
III.41g/mol


93
 I.edbdf cccbe bc
II.abcab acddd
IV.(a)k=0.01/MS ; t=10000s
   (b)5x10^-4M
   (c)3x10^-6M/s


92
  I.CACBB DACDD DBAAD CBDAD ABBDC BABDD
 II.AABB 72kJ
III.BO=2
 IV.(a)5.5
    (b)5
    (c)150


91
 1.D   D   ABE BE  ACD
 6.CD  BD  AB  ACD ABC
11.ACE ABCD


=普化C=
98
DDEEB DCCCA CBCCC ACDDB

97
I
 1.d bc c b  b
 6.c c  c a  c
11.a ad c c  d
16.b d  d ac b
II
1.(b)1
  (c)diamagnetic
2.(b)paramagnetic
  (c)high-spin
3.(b)1.08V
  (c)-625320J
  (d)0


96
AACCC  BACAA BACAC BBBBA

95
cacac ccbbd ecdcb dcacc

94
daaec dbead caedb bccba

93
bcccc bbc

92
AAABD DBCAE CCDAC ABEDB

91
ACADB CBCAD BBCAB DCBDD CDDAB
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※ 編輯: YapYap          來自: 112.104.0.168        (08/02 10:17)