Venus Williams (USA) [1] vs bye
Klara Koukalova (CZE) [Q] vs Patty Schnyder (SUI)
Anastasia Myskina (RUS) vs Samantha Stosur (AUS) [WC]
Marlene Weingartner (GER) vs Ai Sugiyama (JPN) [8]

Meghann Shaughnessy (USA) [4] vs Nuria Llagostera Vives (ESP) [Q]
Nadia Petrova (RUS) vs Cristina Torrens Valero (ESP)
Irina Selyutina (KAZ) vs Yoon Jeong Cho (KOR) [Q]
Emilie Loit (FRA) vs Silvia Farina Elia (ITA) [5]

Daja Bedanova (CZE) [7] vs Christina Wheeler (AUS) [WC]
Joannette Kruger (RSA) vs Iva Majoli (CRO)
Elena Likhovtseva (RUS) vs Alexandra Stevenson (USA)
Tina Pisnik (SLO) vs Sandrine Testud (FRA) [3]

Rita Grande (ITA) [6] vs Anca Barna (GER) [Q]
Nicole Pratt (AUS) vs Lilia Osterloh (USA)
Bianka Lamade (GER) vs Daniela Hantuchova (SVK)
Justine Henin (BEL) [2] vs bye