Kim Clijsters (BEL) [1] vs bye
Maria Elena Camerin (ITA) [Q] vs Marta Marrero (ESP) [Q]
Anna-Lena Groenefeld (GER) [WC] vs Karolina Sprem (CRO)
Meghann Shaughnessy (USA) vs Jelena Dokic (SCG) [15]

Vera Zvonareva (RUS) [9] vs Tatiana Perebiynis (UKR) [Q]
Fabiola Zuluaga (COL) vs Sandrine Testud (FRA)
Mary Pierce (FRA) vs Elena Likhovtseva (RUS)
Ai Sugiyama (JPN) [8] vs bye

Venus Williams (USA) [3] vs bye
Tatiana Golovin (FRA) [Q] vs Eleni Daniilidou (GRE)
Nathalie Dechy (FRA) vs Barbora Strycova (CZE) [Q]
Magdalena Maleeva (BUL) vs Anna Smashnova-Pistolesi (ISR) [16]

Paola Suarez (ARG) [11] vs Anabel Medina Garrigues (ESP) [Q]
Barbara Schett (AUT) vs Katarina Srebotnik (SLO) [LL]
Anca Barna (GER) vs Nicole Pratt (AUS)
Nadia Petrova (RUS) [5] vs bye



Jennifer Capriati (USA) [6] vs bye
Julia Schruff (GER) [WC] vs Meilen Tu (USA) [Q]
Julia Vakulenko (UKR) [LL] vs Petra Mandula (HUN)
Dinara Safina (RUS) vs Maria Sharapova (RUS) [17]

Patty Schnyder (SUI) [13] vs Daniela Hantuchova (SVK)
Emmanuelle Gagliardi (SUI) [Q] vs Cara Black (ZIM)
Jelena Kostanic (CRO) [Q] vs Tina Pisnik (SLO)
Anastasia Myskina (RUS) [4] vs bye

Elena Dementieva (RUS) [7] vs bye
Stephanie Gehrlein (GER) [WC] vs Stephanie Cohen-Aloro (FRA) [Q]
Zi Yan (CHN) [Q] vs Elena Bovina (RUS)
Marie-Gayanay Mikaelian (SUI) [WC] vs Svetlana Kuznetsova (RUS) [10]

Conchita Martinez (ESP) [14] vs Maria Sanchez Lorenzo (ESP)
Arantxa Parra Santonja (ESP) vs Denisa Chladkova (CZE)
Michaela Pastikova (CZE) [Q] vs Gisela Dulko (ARG)
Amelie Mauresmo (FRA) [2] vs bye