Serena Williams (USA) [1] vs bye
Sandrine Testud (FRA) vs Maria Sanchez Lorenzo (ESP)
Vera Douchevina (RUS) [Q] vs Cara Black (ZIM)
Dally Randriantefy (MAD) [Q] vs Magdalena Maleeva (BUL) [15]

Svetlana Kuznetsova (RUS) [9] vs Alicia Molik (AUS)
Marta Marrero (ESP) [Q] vs Tatiana Panova (RUS) [Q]
Gisela Dulko (ARG) [Q] vs Mary Pierce (FRA)
Ai Sugiyama (JPN) [7] vs bye

Nadia Petrova (RUS) [4] vs bye
Laura Granville (USA) vs Flavia Pennetta (ITA) [WC]
Maria Elena Camerin (ITA) [WC] vs Jelena Dokic (SCG)
Magui Serna (ESP) vs Anna Smashnova-Pistolesi (ISR) [16]

Paola Suarez (ARG) [12] vs Fabiola Zuluaga (COL)
Jill Craybas (USA) vs Tatiana Golovin (FRA) [Q]
Klara Koukalova (CZE) [Q] vs Maria Vento-Kabchi (VEN)
Jennifer Capriati (USA) [5] vs bye



Vera Zvonareva (RUS) [8] vs bye
Dinara Safina (RUS) vs Mara Santangelo (ITA) [WC]
Elena Bovina (RUS) vs Tina Pisnik (SLO)
Anca Barna (GER) vs Patty Schnyder (SUI) [11]

Francesca Schiavone (ITA) [14] vs Nicole Pratt (AUS)
Samantha Reeves (USA) [Q] vs Lisa Raymond (USA)
Emilie Loit (FRA) vs Elena Likhovtseva (RUS)
Anastasia Myskina (RUS) [3] vs bye

Elena Dementieva (RUS) [6] vs bye
Tatiana Perebiynis (UKR) [Q] vs Maria Sharapova (RUS)
Jelena Kostanic (CRO) [Q] vs Meghann Shaughnessy (USA)
Barbara Schett (AUT) [Q] vs Silvia Farina Elia (ITA) [10]

Conchita Martinez (ESP) [13] vs Yuliana Fedak (UKR) [Q]
Karolina Sprem (CRO) vs Daniela Hantuchova (SVK)
Nathalie Dechy (FRA) vs Kristina Brandi (PUR)
Amelie Mauresmo (FRA) [2] vs bye