[1] Lindsay Davenport (USA) vs Bye
[WC] Jill Craybas (USA) vs [Q] Marie-Eve Pelletier (CAN)
[Q] Kristina Brandi (PUR) vs [Q] Viktoriya Kutuzova (UKR)
[Q] Severine Beltrame (FRA) vs [16] Fabiola Zuluaga (COL)

[10] Jelena Jankovic (SCG) vs Justine Henin-Hardenne (BEL)
Peng Shuai (CHN) vs Marissa Irvin (USA)
Iveta Benesova (CZE) vs [Q] Galina Voskoboeva (RUS)
[6] Vera Zvonareva (RUS) vs Bye

[4] Venus Williams (USA) vs Bye
Denisa Chladkova (CZE) vs Maria Elena Camerin (ITA)
Virginie Razzano (FRA) vs Lisa Raymond (USA)
Amy Frazier (USA) vs [13] Tatiana Golovin (FRA)

[12] Silvia Farina Elia (ITA) vs Jelena Kostanic (CRO)
Barbora Strycova (CZE) vs Conchita Martinez (ESP)
Akiko Morigami (JPN) vs Tathiana Garbin (ITA)
[7] Nadia Petrova (RUS) vs Bye



[8] Patty Schnyder (SUI) vs Bye
Marta Marrero (ESP) vs Anabel Medina Garrigues (ESP)
Samantha Stosur (AUS) vs Virginia Razzano Pascual (ESP)
Klara Koukalova (CZE) vs [9] Elena Likhovtseva (RUS)

[14] Shinobu Asagoe (JPN) vs [Q] Lindsay Lee-Waters (USA)
[WC] Eleni Daniilidou (GRE) vs Meghann Shaughnessy (USA)
[Q] Shahar Peer (ISR) vs Nicole Vaidisova (CZE)
[3] Anastasia Myskina (RUS) vs Bye

[LL] Tatiana Perebiynis (UKR) vs Bye
[WC] Nicole Pratt (AUS) vs Katarina Srebotnik (SLO)
[WC] Carly Gullickson (USA) vs Anna-Lena Groenefeld (GER)
[Q] Yuliana Fedak (UKR) vs [11] Ai Sugiyama (JPN)

[15] Mary Pierce (FRA) vs Mashona Washington (USA)
Nuria Llagostera Vives (ESP) vs Martina Sucha (SVK)
Dally Randriantefy (MAD) vs Alina Jidkova (RUS)
[2] Elena Dementieva (RUS) vs Bye