[1] Maria Sharapova (RUS) vs Bye
Shahar Peer (ISR) vs Vera Douchevina (RUS)
Li Na (CHN) vs Jill Craybas (USA)
Shinobu Asagoe (JPN) vs [7] Tatiana Golovin (FRA)

[4] Serena Williams (USA) vs Bye
[Q] Tatiana Panova (RUS) vs [WC] Sun Tiantian (CHN)
Maria Kirilenko (RUS) vs [Q] Jamea Jackson (USA)
[Q] Aika Nakamura (JPN) [8] Flavia Pennetta (ITA)

[6] Jelena Jankovic (SCG) vs [WC] Zheng Jie (CHN)
Meghann Shaughnessy (USA) vs Marta Domachowska (POL)
Nuria Llagostera Vives (ESP) vs [LL] Alina Jidkova (RUS)
[3] Venus Williams (USA) vs Bye

[5] Alicia Molik (AUS) vs Mariana Diaz-Olica (ARG)
[Q] Emma Laine (FIN) vs Peng Shuai (CHN)
Akiko Morigami (JPN) vs [WC] Ai Sugiyama (JPN)
[9] Anna-Lena Groenefeld (GER) vs Bye