Serena Williams (USA) [1] vs bye
Sabine Appelmans (BEL) vs Martina Muller (GER) [WC]
Gala Leon Garcia (ESP) vs Sonya Jeyaseelan (CAN) [Q]
Raluca Sandu (ROM) [WC] vs Patty Schnyder (SUI) [8]

Amelie Mauresmo (FRA) [3] vs bye
Tina Pisnik (SLO) [LL] vs Silvia Farina (ITA)
Kveta Hrdlickova (CZE) vs Anna Smashnova (ISR)
Karina Habsudova (SVK) vs Ruxandra Dragomir (ROM) [6]

Silvija Talaja (CRO) [7] vs Anne Kremer (LUX)
Miriam Oremans (NED) [Q] vs Irina Spirlea (ROM)
Denisa Chladkova (CZE) vs Amanda Hopmans (NED) [Q]
Elena Likhovtseva (RUS) [4] vs bye

Anke Huber (GER) [5] vs Kim Clijsters (BEL)
Amelie Cocheteux (FRA) [LL] vs Anne-Gaelle Sidot (FRA)
Natasha Zvereva (BLR) vs Kristie Boogert (NED) [Q]
Nathalie Tauziat (FRA) [2] vs bye